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DECOMPOSITION OF DITHIOCARBAMATES. III. ETHYLDITHIOCARBAMIC ACID IN CONCENTRATED SULFURIC ACID SOLUTIONS
- Source :
- Chemistry Letters; February 1972, Vol. 1 Issue: 2 p159-162, 4p
- Publication Year :
- 1972
-
Abstract
- The UV spectral changes and decomposition rates of ethyldithio-carbamic acid (I) were investigated in sulfuric acid solutions. The presence of the S-protonated form (IV) was established. The observed first-order rate constants fit with the rate expression, kobs= kK/(h0+ K), derivable from the proposed mechanism, IV\oversetK⇔I \oversetk→ EtNH2+ CS2.
Details
- Language :
- English
- ISSN :
- 03667022 and 13480715
- Volume :
- 1
- Issue :
- 2
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Periodical
- Accession number :
- ejs64652394
- Full Text :
- https://doi.org/10.1246/cl.1972.159