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Facile Syntheses of cis-Fused Carbobicycles viaCombination of Claisen Rearrangement of Macrolactone and Nitrile Oxide Cycloaddition

Authors :
Suh, Young-Ger
Kim, Soon-Ai
Cho, Hyun-Uk
Cho, Youn-Sang
Source :
Chemistry Letters; January 1994, Vol. 23 Issue: 1 p63-66, 4p
Publication Year :
1994

Abstract

cis-Bicyclo[3.3.0]octanone, cis-hydrindanone and cis-decalone skeletons have been efficiently constructed by intramolecular nitrile oxide-olefin cycloaddition of 1-ethenyl-2-nitroalkyl cycloalkanes or 1-ethenyl-2-hydroxyiminoalkyl cycloalkane which are readily derived from macrolactone by Funk’s Claisen rearrangement.

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
23
Issue :
1
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64651653
Full Text :
https://doi.org/10.1246/cl.1994.63