Back to Search Start Over

Formation of Dithioacetals by Treatment of Sulfoxides Carrying α-Hydrogens with Magnesium Amides

Authors :
Kobayashi, Kazuhiro
Kawakita, Masataka
Mannami, Tohru
Morikawa, Osamu
Konishi, Hisatoshi
Source :
Chemistry Letters; August 1994, Vol. 23 Issue: 8 p1551-1554, 4p
Publication Year :
1994

Abstract

Sulfoxides carrying α-hydrogens were allowed to react with magnesium amides generated in situ by the treatment of ethylmagnesium bromide with secondary amines such as 2,2,6,6-tetramethylpiperidine or diisopropylamine in diethyl ether to give the corresponding dithioacetals in moderate to good yields.

Details

Language :
English
ISSN :
03667022 and 13480715
Volume :
23
Issue :
8
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Periodical
Accession number :
ejs64651589
Full Text :
https://doi.org/10.1246/cl.1994.1551