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Photolysis of anti-Dodecaalkyltricyclo[4.2.0.02,5]octasilane: Generation and Reactions of Cyclotetrasilene
- Source :
- Chemistry Letters; May 2000, Vol. 29 Issue: 5 p494-495, 2p
- Publication Year :
- 2000
-
Abstract
- The photolysis of tricyclic ladder oligosilanes gave a cyclotetrasilene intermediate, which was trapped by methanol, 2,3-dimethyl-1,3-butadiene, and anthracene. Anthracene underwent a cycloaddition with the cyclotetrasilenes at the 9,10- and 1,4-positions depending on the substituents on the cyclotetrasilene rings.
Details
- Language :
- English
- ISSN :
- 03667022 and 13480715
- Volume :
- 29
- Issue :
- 5
- Database :
- Supplemental Index
- Journal :
- Chemistry Letters
- Publication Type :
- Periodical
- Accession number :
- ejs64649815
- Full Text :
- https://doi.org/10.1246/cl.2000.494