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Pyrolysis of Fluorinated Organic Compounds. I. The Pyrolysis of 1, 2-Dibromo-1-chloro-1, 2, 2-trifluoroethane and Some Related Halogenated Ethane Derivatives

Authors :
Park, J D
Lamb, R W
Lacher, J R
Source :
Bulletin of the Chemical Society of Japan; July 1964, Vol. 37 Issue: 7 p946-950, 5p
Publication Year :
1964

Abstract

The synthesis of various halogenated ethane derivatives was performed by the pyrolysis of CF2Br-CFClBr and other similar compound. The reactions were carried out in a platinumlined tube at temperatures ranging from 350°C to 600°C alone and in the presence of nitric oxide or bromine. Various products were isolated and identified. A mechanism is postulated for the reaction.

Details

Language :
English
ISSN :
00092673 and 13480634
Volume :
37
Issue :
7
Database :
Supplemental Index
Journal :
Bulletin of the Chemical Society of Japan
Publication Type :
Periodical
Accession number :
ejs64634192
Full Text :
https://doi.org/10.1246/bcsj.37.946