Dendrite-Free Lithium Metal Anodes Enabled by an Ordered Conductive Ni-Based Catecholate Interlayer for Solid-State Lithium Batteries

The large-scale commercial application of Li metal batteries is hindered by uncontrolled Li dendrite growth. Most of the present interfacial engineering strategies in lithium metal batteries can only prolong the nucleation time of lithium dendrites but cannot prevent the growth of lithium dendrites in three-dimensional space. In this work, a nickel-based catecholate (Ni-CAT) conductive interlayer that can guide the orderly migration of lithium ions and inhibit the disordered deposition of lithium dendrites is successfully constructed between the solid electrolyte and lithium metal through a reasonable design. The experimental analysis proves that the Ni-CAT nanorod arrays with unique vertical structures are closely connected to the solid electrolyte, which can reduce the charge-transfer resistance at the interface and guide lithium ions to be preferentially deposited on the surface of the Ni-CAT intermediate layer through the conduction gradient. Hence, this structure effectively avoids the phenomenon of apical growth during lithium deposition. In addition, the rich pores and inherent nanochannels of Ni-CAT itself act as an “ion sieve”, successfully inducing the uniform deposition of lithium metal, which greatly reduces the occurrence of dead lithium due to the loss of electrical contact of lithium during cycling. This strategy holds promise for solving the lithium dendrite problem.