Back to Search
Start Over
Electron ionization mass spectrometry as a tool for the investigation of the ortho effect in fragmentation of some Schiff bases derived from amphetamine analogsPart of this work was presented at the XXIst Informal Meeting on Mass Spectrometry, Antwerp, 2003
- Source :
- Journal of Mass Spectrometry; August 2004, Vol. 39 Issue: 8 p966-972, 7p
- Publication Year :
- 2004
-
Abstract
- The electron ionization‐induced fragmentation patterns of three forensically relevant Schiff bases, originating from the condensation between 2‐, 3‐ and 4‐methoxyamphetamine and the corresponding ketones, were studied. The proposed fragmentation routes and ion structures are supported by high‐resolution data and B/E linked‐scan and mass‐analyzed ion kinetic energy spectra. The rationalization of the ortho effect, which is responsible for the formation of the [M − OCH3] fragment in the case of the imine bearing ortho‐substituted methoxy group, is given. Copyright © 2004 John Wiley & Sons, Ltd.
Details
- Language :
- English
- ISSN :
- 10765174 and 10969888
- Volume :
- 39
- Issue :
- 8
- Database :
- Supplemental Index
- Journal :
- Journal of Mass Spectrometry
- Publication Type :
- Periodical
- Accession number :
- ejs6336465
- Full Text :
- https://doi.org/10.1002/jms.633