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P-T-xMeasurement and Modeling of Methane + Propane + Methanol or 2,2′-[Ethane-1,2-diylbis(oxy)] Di(ethan-1-ol) and Methane + Propane + Methanol + 2,2′-[Ethane-1,2-diylbis(oxy)] Di(ethan-1-ol) Systems
- Source :
- Journal of Chemical and Engineering Data; November 2023, Vol. 68 Issue: 11 p2871-2887, 17p
- Publication Year :
- 2023
-
Abstract
- Limited phase equilibria data exist for multicomponent systems encountered in the natural gas processing industry. To address this gap, bubble point measurements were performed for methane + propane + methanol; methane + propane + (2,2′-[ethane-1,2-diylbis(oxy)] di(ethan-1-ol) or triethylene glycol); methane + propane + methanol + triethylene glycol systems in the temperature range of 283.16 to 323.16 K and a pressure range of 0.78 to 13.79 MPa. A visual synthetic high-pressure cell comprising a sapphire tube of 33 cm3working volume was used. The new experimental P-T-xdata were modeled using the Cubic Plus Association (CPA) model and the Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) model. Model correlations with the CPA model yielded better results than those with the PC-SAFT model, with a maximum absolute average relative deviation in pressure of 6.97% and 7.33%, respectively. The CPA model predictions based on binary parameters alone do not adequately describe phase behavior of multicomponent systems.
Details
- Language :
- English
- ISSN :
- 00219568 and 15205134
- Volume :
- 68
- Issue :
- 11
- Database :
- Supplemental Index
- Journal :
- Journal of Chemical and Engineering Data
- Publication Type :
- Periodical
- Accession number :
- ejs62458461
- Full Text :
- https://doi.org/10.1021/acs.jced.2c00776