Back to Search
Start Over
The Nitrate and Nitrocarbamate of 1,3,5-Trinitrocyclohexane-trimethanol and Selected Salts
- Source :
- The Journal of Organic Chemistry; February 2023, Vol. 88 Issue: 4 p2425-2432, 8p
- Publication Year :
- 2023
-
Abstract
- With 1,3,5-trinitrocyclohexane-1,3,5-triyl trimethanol as a precursor, available from 1,3,5-trinitrobenzene, two further nitro-containing molecules were synthesized. Via modification of the hydroxyl groups, new oxygen-rich compounds were obtained, the corresponding trinitrate and trinitrocarbamate. From the latter, various salts were obtained by treatment with bases. All compounds were fully characterized by NMR and IR spectroscopy, X-ray diffraction, and elemental and differential thermal analyses. Moreover, the sensitivity toward friction and impact was determined according to BAM standard techniques and the energetic properties were calculated by using the EXPLO5 computer code.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 88
- Issue :
- 4
- Database :
- Supplemental Index
- Journal :
- The Journal of Organic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs62088000
- Full Text :
- https://doi.org/10.1021/acs.joc.2c02849