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Effect of SEI Component on Graphite Electrode Performance for Li-Ion Battery Using Ionic Liquid Electrolyte

Authors :
Nakatani, Naoki
Kishida, Kazuhisa
Nakagawa, Kiyoharu
Source :
Journal of the Electrochemical Society; January 2018, Vol. 165 Issue: 9
Publication Year :
2018

Abstract

In this study, we investigated the role of solid electrolyte interface (SEI) films in the cells fabricated with the ionic liquids ([N2,2,1(2O1)][TFSI] and [Li(G4)][TFSI]). The SEI was introduced beforehand to the graphite electrode, which facilitated the intercalation of Li-ions into the graphite electrode in [Li(G4)][TFSI]. In addition, the discharge capacity in the case of the cell fabricated with [Li(G4)][TFSI] was almost similar to that observed in the case of the cell fabricated with organic electrolyte. The SEI performed the pulling apart combination of glyme and Li-ion. Identification analysis of the SEI component having action of extracting Li-ion from [Li(G4)] was carried out.

Details

Language :
English
ISSN :
00134651 and 19457111
Volume :
165
Issue :
9
Database :
Supplemental Index
Journal :
Journal of the Electrochemical Society
Publication Type :
Periodical
Accession number :
ejs61771982
Full Text :
https://doi.org/10.1149/2.0361809jes