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Chemoenzymatic one-pot reaction from carboxylic acid to nitrile viaoximeElectronic supplementary information (ESI) available. See DOI: 10.1039/d1cy01694f

Authors :
Horvat, Melissa
Weilch, Victoria
Rädisch, Robert
Hecko, Sebastian
Schiefer, Astrid
Rudroff, Florian
Wilding, Birgit
Klempier, Norbert
Pátek, Miroslav
Martínková, Ludmila
Winkler, Margit
Source :
Catalysis Science & Technology; 2022, Vol. 12 Issue: 1 p62-66, 5p
Publication Year :
2022

Abstract

We report a new chemoenzymatic cascade starting with aldehyde synthesis by carboxylic acid reductase (CAR) followed by chemical in situoxime formation. The final step to the nitrile is catalyzed by aldoxime dehydratase (Oxd). Full conversions of phenylacetic acid and hexanoic acid were achieved in a two-phase mode.

Details

Language :
English
ISSN :
20444753 and 20444761
Volume :
12
Issue :
1
Database :
Supplemental Index
Journal :
Catalysis Science & Technology
Publication Type :
Periodical
Accession number :
ejs58621883
Full Text :
https://doi.org/10.1039/d1cy01694f