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In situ Bi/carboxyphenyl-modified glassy carbon electrode as a sensor platform for detection of Cd2+and Pb2+using square wave anodic stripping voltammetry.
- Source :
- Sensing and Bio-Sensing Research; 20210101, Issue: Preprints
- Publication Year :
- 2021
-
Abstract
- Herein, a sensor platform, Bi/carboxyphenyl-modified glassy carbon electrode (Bi/CP/GCE), is presented for the detection of Cd2+and Pb2+using square wave anodic stripping voltammetry (SWASV). The sensor was obtained through electrografting of the GCE using 4-carboxybenzene diazonium tetrafluoroborate (4-CBD) and in situ electrodeposition of Bi3+. The stability of the grafted layer and the proposed mechanism of interaction between the metal ions and the grafted layer is supported by DFT calculations. Under the optimized conditions, Pb2+had a linear working range of 25–500 μg L−1with LOD of 10 μg L−1(S/N = 3) and Cd2+provided linear range of 50–500 μg L−1and LOD of 25 μg L−1. The fabricated electrode presented good repeatability and reproducibility. The applicability of the electrode was tested for determination of Cd2+and Pb2+in tap water resulting in recoveries of 96.2–101% for Cd2+and 98.1–104% for Pb2+.
Details
- Language :
- English
- ISSN :
- 22141804
- Issue :
- Preprints
- Database :
- Supplemental Index
- Journal :
- Sensing and Bio-Sensing Research
- Publication Type :
- Periodical
- Accession number :
- ejs57917940
- Full Text :
- https://doi.org/10.1016/j.sbsr.2021.100455