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Evolution of Temperature-Induced Isostructural Phase Transition in a Newly Grown Layered FeTe2Single Crystal
- Source :
- Chemistry of Materials; 20210101, Issue: Preprints
- Publication Year :
- 2021
-
Abstract
- Layered FeTe2(l-FeTe2) was supposed to be one of the most important compounds in the family of two-dimensional transition-metal dichalcogenides (2D TMDs) owing to the importance of an iron element and its predicted novel physical phenomena. However, 2D layered FeTe2is rarely reported because of its tendency to be stabilized in three-dimensional marcasite phase structures. Here, we report, for the first time, a pure and large-size l-FeTe2single crystal synthesized successfully in a P3̅m1 hexagonal space group using a solid-state reaction method. Thermoanalysis and X-ray diffraction (XRD) data after annealing at different temperatures indicate that l-FeTe2is a metastable material. The results of electrical transport, magnetization, and in situ low-temperature XRD measurements confirm that l-FeTe2undergoes a first-order isostructural phase transition from 120 to 150 K, and we established a detailed correlation among these properties of l-FeTe2. l-FeTe2transforms from an insulating to metallic state at 120 K where the phase transition completes. In addition, the Shubnikov–de Haas (SdH) oscillation phenomenon is observed under a high magnetic field at 4 K.
Details
- Language :
- English
- ISSN :
- 08974756
- Issue :
- Preprints
- Database :
- Supplemental Index
- Journal :
- Chemistry of Materials
- Publication Type :
- Periodical
- Accession number :
- ejs56821379
- Full Text :
- https://doi.org/10.1021/acs.chemmater.1c00467