Efficient SO2Removal and Highly Synergistic H2O2Production Based on a Novel Dual-Function Photoelectrocatalytic System

The direct conversion of SO2to SO3is rather difficult for flue gas desulfurization due to its inert dynamic with high reaction activation energy, and the absorption by wet limestone-gypsum also needs the forced oxidation of O2to oxidize sulfite to sulfate, which is necessary for additional aeration. Here, we propose a method to remove SO2with highly synergistic H2O2production based on a novel dual-function photoelectrocatalytic (PEC) system in which the jointed spontaneous reaction of desulfurization and H2O2production was integrated instead of nonspontaneous reaction of O2to H2O2. SO2was absorbed by alkali liquor then oxidized quickly into SO42–by a nanorod α-Fe2O3photoanode, which possessed high alkali corrosion resistance and electron transport properties. H2O2was produced simultaneously in the cathode chamber on a gas diffusion electrode and was remarkably boosted by the conversion reaction of SO32–to SO42–in the anode chamber in which the released chemical energy was effectively used to increase H2O2. The photocurrent density increased by 40% up to 1.2 mA·cm–2, and the H2O2evolution rate achieved 58.8 μmol·L–1·h–1·cm–2with the synergistic treatment of SO2, which is about five times than that without SO2. This proposed PEC cell system offers a cost-effective and environmental-benign approach for dual purpose of flue gas desulfurization and simultaneous high-valued H2O2production.