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Benign Solvation Effect on Electrochemical Intercalation of Triethylmethyl Ammonium into Graphite from Propylene Carbonate
- Source :
- Journal of the Electrochemical Society; January 2018, Vol. 165 Issue: 16 pA4012-A4017, 6p
- Publication Year :
- 2018
-
Abstract
- Tetraethyl ammonium/triethylmethyl ammonium tetrafluoroborates dissolved in propylene carbonate (PC) are the most common non-aqueous electrolyte solutions for supercapacitors using both carbonaceous electrodes. In this work, they are applied in the graphite/activated carbon asymmetric capacitors, in which the charge storage at graphite negative electrode is based on the intercalation of quaternary alkyl ammonium cations. The capacitor containing triethylmethyl ammonium (TEMA+) shows a much higher capacity and superior cycle-ability than that containing tetraethyl ammonium (TEA+). In situ X-ray diffraction and in situ dilatometry are combined to determine the larger recoverable expansion in graphite negative electrodes due to a reversible intercalation of TEMA+. Electrochemical quartz crystal microbalance verifies the dramatic structural changes stem from the considerable co-intercalation PC molecules together with TEMA+. A benign solvation effect is proposed for facilitating the transportation and storage of TEMA+ inside graphite.
Details
- Language :
- English
- ISSN :
- 00134651 and 19457111
- Volume :
- 165
- Issue :
- 16
- Database :
- Supplemental Index
- Journal :
- Journal of the Electrochemical Society
- Publication Type :
- Periodical
- Accession number :
- ejs52677833