Selective Electrocatalytic Water Oxidation to Produce H2O2Using a C,N Codoped TiO2Electrode in an Acidic Electrolyte

Production of hydrogen peroxide (H2O2) via in situ electrochemical water oxidation possesses great potential applications in the energy and environment fields. In this work, for the first time, we reported a C,N codoped TiO2electrode for selective electrocatalytic water oxidation to produce H2O2in an acidic electrolyte. An electrochemical anodic oxidation method combined with postcalcination in the presence of urea was applied to fabricate such a C,N codoped TiO2electrode, which was evidenced by detail structural characterizations. The calcination temperature and urea atmosphere were found to play key roles in its catalytic performances; the optimized 600N sample exhibited an onset potential of 2.66 V (vs Ag/AgCl) and a Tafel slope of 51 mV dec–1at pH 3. Under the optimal applied potential, the cumulative H2O2concentration for this sample reached 0.29 μmol L–1cm–2h–1. More importantly, a simple recalcination strategy was developed to recover the deactivation electrode. This study proposed an efficient C,N codoped TiO2electrode toward water oxidation to selectively produce H2O2in the acidic electrolyte, which could be further used to in situ generate H2O2for the energy- and environment-related fields with water as the precursor.