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“Boarding-Up”: Radiation Damage and Radionuclide Leaching Kinetics in Linker-Capped Metal–Organic Frameworks
- Source :
- Inorganic Chemistry; January 2020, Vol. 59 Issue: 1 p179-183, 5p
- Publication Year :
- 2020
-
Abstract
- For the first time, we report the ability to control radionuclide species release kinetics in metal–organic frameworks (MOFs) as a function of postsynthetic capping linker installation, which is essential for understanding MOF potential as viable radionuclide wasteform materials or versatile platforms for sensing, leaching, and radionuclide sequestration. The radiation damage of prepared frameworks under γ radiation has also been studied. We envision that the presented studies are the first steps toward utilization of the reported scaffolds for more efficient nuclear waste administration.
Details
- Language :
- English
- ISSN :
- 00201669 and 1520510X
- Volume :
- 59
- Issue :
- 1
- Database :
- Supplemental Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs50465527
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.9b01310