Toward Supertough and Heat-Resistant Stereocomplex-Type Polylactide/Elastomer Blends with Impressive Melt Stability via in SituFormation of Graft Copolymer during One-Pot Reactive Melt Blending

Stereocomplexation of enantiomeric poly(l-lactide)/poly(d-lactide) (PLLA/PDLA) chains opens up a great opportunity toward sustainable PLA engineering plastic with exceptional heat resistance and durability. However, the processing and applications of stereocomplex-type PLA (SC-PLA) are significantly blocked by its inferior melt stability (i.e., the weak melt memory effect in triggering complete SC crystallization, which makes it hard to obtain exclusive formation of SC crystallites in melt-processed products) and inherent brittleness. In this contribution, we demonstrate an unprecedented strategy to address these obstacles by one-pot reactive melt blending of the equimolar PLLA/PDLA blend with reactive poly(ethylene–methyl acrylate–glycidyl methacrylate) (E-MA-GMA) in the presence of catalyst, where both the stereocomplexation and the grafting of some PLLA/PDLA chains onto E-MA-GMA backbones take place simultaneously and competitively. Intriguingly, the E-MA-graft-PLA copolymer in situformed can substantially improve the melt stability of SC-PLA matrix as compatibilizer, and thus highly crystalline SC-PLA/E-MA-GMA blend products with exclusive SC crystallites can be readily obtained by injection molding. Moreover, some E-MA-graft-PLA can also strengthen the blend interface as interfacial enhancer, which gives rise to an increase in the toughening efficiency. As a result, the obtained SC-PLA/E-MA-GMA blends exhibits impressive heat resistance (the Vicat softening temperature and heat deflection temperature are as high as 201 and 174 °C, respectively) and impact toughness (the notched Izod impact strength is close to 65 kJ/m2). Notably, their comprehensive performance is superior to some commercial petroleum-derived engineering plastics. Overall, the one-pot syntheses of copolymer by in situgrafting could open up a new horizon for creating super-robust SC-PLA-based engineering plastic using industrial melt-processing technologies.