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Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis
- Source :
- Inorganic Chemistry; January 2019, Vol. 58 Issue: 2 p1201-1207, 7p
- Publication Year :
- 2019
-
Abstract
- A commercially available and stable ruthenium dodecacarbonyl catalyst (Ru3(CO)12) allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si–O–Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as C═C and C═N hydrosilylation.
Details
- Language :
- English
- ISSN :
- 00201669 and 1520510X
- Volume :
- 58
- Issue :
- 2
- Database :
- Supplemental Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs48080395
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.8b02645