High-Quality Reduced Graphene Oxide Electrodes for Sub-Kelvin Studies of Molecular Monolayer Junctions

Electron transport phenomena in molecular monolayers are complex and potentially different from those of single molecules because of, for example, molecule–molecule interactions. Unfortunately, access to detailed mechanistic investigations of molecular monolayer junctions at ultralow temperatures is typically hampered by the narrow range of operating temperatures for most large-area device platforms. Here, we present a highly optimized chemically derived graphene material with a near temperature-independent conductance profile. Using this material as a conducting interlayer electrode in solid-state molecular electronic devices, we show robust and reliable large-area molecular junction operation at temperatures ranging from room temperature to below 1 K, and we demonstrate the ability to measure inelastic electron tunneling spectroscopy of a conjugated molecular monolayer at cryogenic temperatures.