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Multimetallic Lanthanide Complexes: Using Kinetic Control To Define Complex Multimetallic Arrays
- Source :
- Accounts of Chemical Research; September 2018, Vol. 51 Issue: 10 p2493-2501, 9p
- Publication Year :
- 2018
-
Abstract
- Kinetically inert lanthanide complexes are proving to be highly effective building blocks for the preparation of complex heterometallic architectures, allowing complete control of metal ion domains, which cannot be achieved under thermodynamic control. Kinetic stability may render perceivable labile coordination bonds more durable than several types of covalent interactions. For complexes in clinical use, the significance of kinetic stability cannot be overstated, and this Account treats the topic accordingly.
Details
- Language :
- English
- ISSN :
- 00014842 and 15204898
- Volume :
- 51
- Issue :
- 10
- Database :
- Supplemental Index
- Journal :
- Accounts of Chemical Research
- Publication Type :
- Periodical
- Accession number :
- ejs46529419
- Full Text :
- https://doi.org/10.1021/acs.accounts.8b00205