Discotic Organic Gelators in Ion Sensing, Metallogel Formation, and Bioinspired Catalysis

Two organogelators G2and G3with a carboxamide group have been synthesized and characterized with different spectroscopic tools. Dimethylformamide or dimethyl sulfoxide solutions of both the compounds upon the addition of a minute quantity of water show the tendency to form gels. Supramolecular self-assembly for gel formation paves the way for aggregation-induced emission enhancement (AIEE) phenomena for both the gelator molecules. Introduction of metal ions in organogels strengthens the gel property without much affecting the fluorescence behavior. However, the introduction of Ag+, Fe2+, and Fe3+ions in the G2organogel separately results in total quenching of AIEE, making it possible to sense that particular cation in the gel state. The G3organogel shows a similar behavior with the Fe2+ion. Remarkably, other metallogels such as Ni(II)G2and Co(II)G2can sense sulfide ion and Cu(II)G2can sense iodide ion by switching off the fluorescence even in multianalyte conditions. Furthermore, the copper-based metallogel Cu(II)G2can be utilized as a catalyst and reaction medium for aerobic oxidation of catechol to quinone. To the best of our knowledge, this is the first attempt known so far to utilize a metallogel material for bioinspired catalysis such as catechol oxidation.