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Zigzag Ligands for Transversal Design in Reticular Chemistry: Unveiling New Structural Opportunities for Metal–Organic Frameworks
- Source :
- Journal of the American Chemical Society; August 2018, Vol. 140 Issue: 32 p10153-10157, 5p
- Publication Year :
- 2018
-
Abstract
- Herein we describe the topological influence of zigzag ligands in the assembly of Zr(IV) metal–organic frameworks (MOFs). Through a transversal design strategy using reticular chemistry, we were able to synthesize a family of isoreticular Zr(IV)-based MOFs exhibiting the bcu—rather than the fcu—topology. Our findings underscore the value of the transversal parameter in organic ligands for dictating MOF architectures.
Details
- Language :
- English
- ISSN :
- 00027863 and 15205126
- Volume :
- 140
- Issue :
- 32
- Database :
- Supplemental Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Periodical
- Accession number :
- ejs46138809
- Full Text :
- https://doi.org/10.1021/jacs.8b07050