Back to Search
Start Over
Investigation into an asymmetric hydrogenation promoted by rhodium-phosphetane complexes
- Source :
- Tetrahedron Letters; January 1999, Vol. 40 Issue: 48 p8365-8368, 4p
- Publication Year :
- 1999
-
Abstract
- The bis-phosphetanes 1and 2have been used as chiral ligands in the rhodium-catalysed hydrogenations of dehydroamino acid derivatives. An unusual increase of the optical yields at high hydrogen pressures has been noticed. Mechanistic implications are discussed.
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 40
- Issue :
- 48
- Database :
- Supplemental Index
- Journal :
- Tetrahedron Letters
- Publication Type :
- Periodical
- Accession number :
- ejs45823694
- Full Text :
- https://doi.org/10.1016/S0040-4039(99)01767-0