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Structure-reactivity studies of the triplet-sensitized photorearrangements of allyl phosphites
- Source :
- Tetrahedron Letters; January 1997, Vol. 38 Issue: 40 p6989-6992, 4p
- Publication Year :
- 1997
-
Abstract
- The relative quantum efficiencies of allylphosphonate ( 7–12) formation, from the triplet-sensitized photorearrangement of allyl phosphites ( 1–6), can be qualitatively correlated using the 1,2-biradical model for π−π ∗excited states and considering the effect on excited state energies and lifetimes of placing the β bond in a small ring.
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 38
- Issue :
- 40
- Database :
- Supplemental Index
- Journal :
- Tetrahedron Letters
- Publication Type :
- Periodical
- Accession number :
- ejs45821257
- Full Text :
- https://doi.org/10.1016/S0040-4039(97)01671-7