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Iodide-Centered Cuprous Octatomic Ring: A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character
- Source :
- Crystal Growth & Design; 20240101, Issue: Preprints
- Publication Year :
- 2024
-
Abstract
- Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu8(HMTZ)(MTZ)7]·MeCN·2H2O (I@Cu8), which consists of an infrequent octatomic [I@Cu8S8] ring. Importantly, compound I@Cu8features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80–300 K, suggesting potential application for a luminescent molecular thermometer.
Details
- Language :
- English
- ISSN :
- 15287483 and 15287505
- Issue :
- Preprints
- Database :
- Supplemental Index
- Journal :
- Crystal Growth & Design
- Publication Type :
- Periodical
- Accession number :
- ejs44229903
- Full Text :
- https://doi.org/10.1021/acs.cgd.7b01261