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Thermophysical Behavior and Temperature Effect on the N-Methylpyrrolidone + (C<INF>1</INF>−C<INF>10</INF>) Alkan-1-ols Mixed Solvents

Authors :
Garcia, B.
Alcalde, R.
Aparicio, S.
Leal, J. M.
Trenzado, J. L.
Source :
Industrial & Engineering Chemistry Research; February 2003, Vol. 42 Issue: 4 p920-928, 9p
Publication Year :
2003

Abstract

Densities and dynamic viscosities of the N-methylpyrrolidone/(C&lt;INF&gt;1&lt;/INF&gt;−C&lt;INF&gt;10&lt;/INF&gt;) alkan-1-ols mixed solvents were measured at atmospheric pressure and 293.15, 303.15, 313.15, and 323.15 K over the whole composition range. The excess and mixing properties deduced from these data were interpreted in terms of intermolecular interactions and structural effects. The Soave−Redlich−Kwong and Peng−Robinson cubic equations of state and the modified extended real associated solution (ERAS) and the Prigogine−Flory−Patterson (PFP) models were used to correlate the excess molar volumes. Several correlation viscosity models were also used in data reduction.

Details

Language :
English
ISSN :
08885885 and 15205045
Volume :
42
Issue :
4
Database :
Supplemental Index
Journal :
Industrial & Engineering Chemistry Research
Publication Type :
Periodical
Accession number :
ejs4307994