Back to Search
Start Over
Adenosine-Phosphate-Fueled, Temporally Programmed Supramolecular Polymers with Multiple Transient States
- Source :
- Journal of the American Chemical Society; 20240101, Issue: Preprints
- Publication Year :
- 2024
-
Abstract
- Natural systems have been an inspiration to synthetic supramolecular chemistry. Synthetic demonstrations of dissipative biological systems such as actin filaments are a formidable scientific challenge in attaining future life-like materials. Dynamic instability of such structures beckons control of self-organization in the temporal regimes. In this study, we present a fuel-dependent helical assembly of a supramolecular polymer. We further attempt the synthetic manifestation of a temporally programmable self-assembly. Additionally, the fuel-induced chiral (re)organization with the employment of various enzymes singularly and in tandem have resulted in designing a multistate transient self-assembly. These parameter modulations result in controllable lifetimes and rates. We thus report, for the first time, a temporally programmed multistate reorganization of self-assembly.
Details
- Language :
- English
- ISSN :
- 00027863 and 15205126
- Issue :
- Preprints
- Database :
- Supplemental Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Periodical
- Accession number :
- ejs43036416
- Full Text :
- https://doi.org/10.1021/jacs.7b07469