Hybrid Polymer Nanoarrays with Bifunctional Conductance of Ions and Electrons and Enhanced Electrochemical Interfaces

Ion migration and electron transfer are crucial phenomena in electrochemistry and interfacial sciences, which require effective coupling and integration of separated charge pathways within medium materials. Here, in this work, we fabricated an ordered nanowire material based on hybrid polymers of polypyrrole, with electronic conductance, and perfluorosulfonic acid ionomers, with ionic conductance, via a facile one-step electrochemical route. Because of the nanoconfined effects for the different charge-transfer channels within the nanowire polymer matrix, the electronic and ionic conductivities of the hybrid polymer are surprisingly enhanced, being 26.4 and 0.096 S cm–1, respectively. Such an improvement in the formation of charge pathways also leads to an increased electrochemical capacitance through enlargement of the area of ion/electron transport boundaries, which may show great potential in the applications of supercapacitors, fuel cells, rechargeable batteries, and other electrochemical devices.