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IrO2-deposited Pt electrocatalysts for unitized regenerative polymer electrolyte fuel cells
- Source :
- Journal of Applied Electrochemistry; November 2001, Vol. 31 Issue: 11 p1179-1183, 5p
- Publication Year :
- 2001
-
Abstract
- An IrO2/Pt electrocatalyst for the polymer electrolyte-type unitized regenerative fuel cell (URFC) was prepared by deposition of iridium oxide (IrO2) particles on Pt black via a colloidal iridium hydroxide hydrate precursor, and URFC performance was examined. After the iridium hydroxide hydrate deposited Pt was calcined at 400 °C in air for 1 h, rutile-structure IrO2particles (20–50 nm dia.) were formed on Pt particle clusters. TEM and pore volume distribution analysis revealed that the microstructure of the deposited IrO2/Pt catalyst was different from the mixed IrO2/Pt catalyst. The cell using the deposited IrO2/Pt (20 at % Ir) catalyst showed similar fuel cell performance with the mixed IrO2/Pt electrode of higher Pt content (10 at % Ir) while maintaining water electrolysis performance. Consequently, 51% round-trip energy conversion efficiency at a current density of 300 mA cm−2was attained.
Details
- Language :
- English
- ISSN :
- 0021891X and 15728838
- Volume :
- 31
- Issue :
- 11
- Database :
- Supplemental Index
- Journal :
- Journal of Applied Electrochemistry
- Publication Type :
- Periodical
- Accession number :
- ejs37086549
- Full Text :
- https://doi.org/10.1023/A:1012755809488