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Hydrothermal synthesis and photocatalytic properties of tantalum pentoxide nanorods
- Source :
- Chinese Journal of Catalysis; March 2015, Vol. 36 Issue: 3 p432-438, 7p
- Publication Year :
- 2015
-
Abstract
- Tantalum pentoxide (Ta2O5) nanorods were hydrothermally synthesized using polyethylene glycol (PEG) as a guiding agent. The nanorods were characterized by X-ray diffraction, scanning and transmission electron microscopies, and diffuse reflectance ultraviolet-visible and photoluminescence spectroscopies. The effects of crystallization duration and Ta2O5/Sr(OH)2ratio on the product morphology were investigated, and a growth mechanism was proposed. Phase-pure Ta2O5nanorods with controlled morphology were formed in the presence of PEG and Sr(OH)2, which was necessary to form the nanorods. Sr(OH)2induced the surface dissolution and re-growth of Ta2O5. PEG induced the anisotropic growth of Ta2O5by acting as a capping agent. The products were used to photocatalytically degrade rhodamine B under ultraviolet irradiation. The catalytic activity directly correlated with the length-diameter ratio of the Ta2O5nanorods. A maximum apparent reaction rate constant of 0.156 min−1was obtained. The Ta2O5nanorods were stable during photocatalytic reaction and could be recycled several times without loss of activity.
Details
- Language :
- English
- ISSN :
- 02539837 and 18722067
- Volume :
- 36
- Issue :
- 3
- Database :
- Supplemental Index
- Journal :
- Chinese Journal of Catalysis
- Publication Type :
- Periodical
- Accession number :
- ejs35470016
- Full Text :
- https://doi.org/10.1016/S1872-2067(14)60215-1