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Bile Pigment Structures, III. Crystal and Molecular Structure of Diethoxybilirubin Diethyl Ester
- Source :
- Zeitschrift für Naturforschung B; November 1979, Vol. 34 Issue: 11 p1542-1546, 5p
- Publication Year :
- 1979
-
Abstract
- Diethoxybilirubin diethyl ester crystallises triclinic P1 with a = 13.903(5), b = 17.211(7), c = 9.831(5) Å, α= 110.07(3), β = 111.22(3), γ = 69.04(3)°, Z = 2, Dx- 1.15 gcm-3. The two pyrromethene systems of the tetrapyrrole are orientated almost perpendicular to one another (interplanar angle = 91.5°). Considerable bond delocalisation is observed within the individual pyrromethene units, which contain intramolecular N-H···N hydrogen bonds of length 2.73 and 2.80 Å. Parallel stacking of the chromophores is not observed in the crystal lattice.
Details
- Language :
- English
- ISSN :
- 09320776 and 18657117
- Volume :
- 34
- Issue :
- 11
- Database :
- Supplemental Index
- Journal :
- Zeitschrift für Naturforschung B
- Publication Type :
- Periodical
- Accession number :
- ejs35057942
- Full Text :
- https://doi.org/10.1515/znb-1979-1112