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Über die Reaktion von [(C0)4FeC(O)NMe2]-[C(NMe2)3]+mit einigen Diorganylbromboranen / On the Reaction of [(C0)4FeC(O)NMe2]-[C(NMe2)3]+with Some Diorganoboron Bromides

Authors :
Petz, W.
Source :
Zeitschrift für Naturforschung B; March 1981, Vol. 36 Issue: 3 p335-338, 4p
Publication Year :
1981

Abstract

The carbamoyl complex [(CO)4FeC(O)NMe2][C(NMe2)3] (1) reacts with boron halides of the type BrBR2(R = Me, Ph, NMe2) at low temperature to give the boroxycarben complexes 2, which decompose at ambient temperature to the aminoboranes 3 and Fe(CO)5. The 1NMR and IR spectra of the new compounds 2 are reported.

Details

Language :
English
ISSN :
09320776 and 18657117
Volume :
36
Issue :
3
Database :
Supplemental Index
Journal :
Zeitschrift für Naturforschung B
Publication Type :
Periodical
Accession number :
ejs35056357
Full Text :
https://doi.org/10.1515/znb-1981-0311