Elektrochemische Synthesen, VI [1]. Elektrochemische Substitution der VIB-Hexacarbonyle M(CO)6(M = Cr, Mo, W) / Electrochemical Syntheses, VI [1]. Electrochemical Substitution of VIB-Hexacarbonyls M(CO)6(M = Cr, Mo, W)

The electrochemical substitution of group VIB hexacarbonyls by solvent molecules and/or phosphane ligands is studied in some detail and is found to be a fruitful alternative preparative route to the well-known photochemical reaction.