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Zur Struktur von (Pyrazolinonyl)-(hydroxypyrazolylium)methanperchloraten NMR-, IR-spektroskopische Studien und Kristallstruktur / The Structure of (Pyrazohnonyl)-(hydroxypyrazolyhum)methaneperchlorates NMR, IR Spectroscopic Studies and Crystal Structure
- Source :
- Zeitschrift für Naturforschung B; March 1983, Vol. 38 Issue: 3 p373-377, 5p
- Publication Year :
- 1983
-
Abstract
- The structures of 1a-1d were investigated by spectroscopic methods and in the case of la in addition by X-ray diffraction, 1a, vicarious for the compounds 1, is stabilized in solution and in the crystal by an intramolecular hydrogen bond in an eight-membered ring. The IR and NMR spectra show that 1 exhibit a symmetrical structure. In the case of 1 a the molecular structure is affected by unsymmetrical packing and electrostatic effects in the crystal and is therefore approximated best between the forms I and II.
Details
- Language :
- English
- ISSN :
- 09320776 and 18657117
- Volume :
- 38
- Issue :
- 3
- Database :
- Supplemental Index
- Journal :
- Zeitschrift für Naturforschung B
- Publication Type :
- Periodical
- Accession number :
- ejs35000585
- Full Text :
- https://doi.org/10.1515/znb-1983-0318