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Structure of NaYF4Upconverting Nanoparticles: A Multinuclear Solid-State NMR and DFT Computational Study

Authors :
Arnold, Alexandre A.
Terskikh, Victor
Li, Qian Ying
Naccache, Rafik
Marcotte, Isabelle
Capobianco, John A.
Source :
The Journal of Physical Chemistry - Part C; December 2013, Vol. 117 Issue: 48 p25733-25741, 9p
Publication Year :
2013

Abstract

The exceptional upconverting properties of lanthanide-doped nanoparticles make them attractive systems with applications ranging from photovoltaics to biological labeling, imaging, and therapeutics. While they draw considerable interest, structural data, which are necessary to understand the upconversion process, remain scarce. In this work, we demonstrate the use of 23Na, 19F, and 89Y solid-state NMR together with DFT calculations to characterize the structure of cubic NaYF4nanoparticles with and without Er3+doping. By measuring 23Na MAS NMR spectra at various magnetic fields and 3QMAS spectra at ultrahigh field, we show that the spectra are characteristic of a solid solution in which cation sites are statistically occupied by Na+or Y3+ions. The 23Na NMR spectra are broadened as a result of isotropic chemical shift distribution, whereas the extracted quadrupolar products appear to be small (≤1.8 MHz), which is in good agreement with DFT calculations using CASTEP. The chemical shift distribution in 19F NMR spectra is well-predicted by CASTEP calculations and shown to strongly depend on coordination by Y3+. Finally, the 89Y NMR spectra consist of a single broad pattern, which also results from a chemical shift distribution that can be correlated to the coordination environment of the Y3+cations. Our results show that the structure is a slightly distorted cubic phase and lanthanide doping has only a minor effect on the lattice parameters. The approach appears to be promising for gaining additional insight into the atomic level structure details to better understand properties that govern the upconversion process and its efficiency.

Details

Language :
English
ISSN :
19327447 and 19327455
Volume :
117
Issue :
48
Database :
Supplemental Index
Journal :
The Journal of Physical Chemistry - Part C
Publication Type :
Periodical
Accession number :
ejs31511666
Full Text :
https://doi.org/10.1021/jp405813a