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A Convenient Synthesis and a NMR Study of the Diammoniate of Diborane

Authors :
Lingam, Hima K.
Chen, Xuenian
Zhao, Ji‐Cheng
Shore, Sheldon G.
Source :
Chemistry - A European Journal; March 2012, Vol. 18 Issue: 12 p3490-3492, 3p
Publication Year :
2012

Abstract

DADB synthesis: The diammoniate of diborane (DADB) was synthesized in a new metathesis reaction between the diammoniate of monochloroborane and potassium borohydride in liquid ammonia (see scheme). 1H and 11B NMR spectra of DADB are reported. The stability in THF was examined by variable‐temperature 11B NMR spectroscopy.

Details

Language :
English
ISSN :
09476539 and 15213765
Volume :
18
Issue :
12
Database :
Supplemental Index
Journal :
Chemistry - A European Journal
Publication Type :
Periodical
Accession number :
ejs27007146
Full Text :
https://doi.org/10.1002/chem.201103693