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Selective Adsorption of CO2from Light Gas Mixtures by Using a Structurally Dynamic Porous Coordination Polymer

Authors :
Kauffman, Kristi L.
Culp, Jeffrey T.
Allen, Andrew J.
Espinal, Laura
Wong‐Ng, Winnie
Brown, Thomas D.
Goodman, Angela
Bernardo, Mark P.
Pancoast, Russel J.
Chirdon, Danielle
Matranga, Christopher
Source :
Angewandte Chemie. International Edition; November 2011, Vol. 50 Issue: 46 p10888-10892, 5p
Publication Year :
2011

Abstract

Flexibility provides selectivity: The selective adsorption of CO2from mixtures with N2, CH4, and N2O in a dynamic porous coordination polymer (see monomer structure) was evaluated by ATR‐FTIR spectroscopy, GC, and SANS. All three techniques indicate highly selective adsorption of CO2from CO2/CH4and CO2/N2mixtures at 30 °C, with no selectivity observed for the CO2/N2O system.

Details

Language :
English
ISSN :
14337851 and 15213773
Volume :
50
Issue :
46
Database :
Supplemental Index
Journal :
Angewandte Chemie. International Edition
Publication Type :
Periodical
Accession number :
ejs26111775
Full Text :
https://doi.org/10.1002/anie.201104130