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Chlorodimethyl(N‐methylpyrrolidinone)tin(IV)‐μ‐chloro‐dichlorodimethyltin(IV)
- Source :
- Acta Crystallographica Section C: Crystal Structure Communications; October 2000, Vol. 56 Issue: 10 pe450-e451, 2p
- Publication Year :
- 2000
-
Abstract
- The synthesis and the X‐ray structural analysis of the title compound, μ‐chloro‐1:2κ2Cl‐tri­chloro‐1κCl,2κ2Cl‐tetra­methyl‐1κ2C,2κ2C‐(N‐methyl­pyrrolidin‐2‐one)‐1κO‐ditin(IV), [Sn2Cl4(CH3)4(C5H9NO)], are described. The title compound is found to exhibit a distorted trigonal–bipyramidal geometry at both SnIVatoms. The Sn—Cl—Sn angle involving the bridging chlorine ligand is 135.56 (5)°, with the Sn—Cl bond lengths being 2.5704 (13) and 3.1159 (13) Å.
Details
- Language :
- English
- ISSN :
- 01082701 and 16005759
- Volume :
- 56
- Issue :
- 10
- Database :
- Supplemental Index
- Journal :
- Acta Crystallographica Section C: Crystal Structure Communications
- Publication Type :
- Periodical
- Accession number :
- ejs24597151
- Full Text :
- https://doi.org/10.1107/S0108270100011963