Tetrakis(5‐tert‐butylpyrazole‐1κN2)tetrachloro‐1κCl,2κ3Cl‐μ‐oxo‐1:2κ2O‐diiron(III)

Authors :: Liu, Xiaoming
Kilner, Colin A.
Halcrow, Malcolm A.
Source :: Acta Crystallographica Section C: Crystal Structure Communications; May 2002, Vol. 58 Issue: 5 pm290-m291, 2p
Publication Year :: 2002
Abstract: The title compound, [Fe2Cl4O(C7H12N2)4], contains vertex‐sharing distorted tetrahedral [FeOCl3]−and octahedral [FeOCl(HpztBu)4]+moieties (HpztBu is 5‐tert‐butylpyrazole), linked by a bent oxo bridging ligand. The two FeIIIcentres are also bridged by intramolecular hydrogen bonds between the pyrazole N—H groups and the O2−and Cl−ligands.

Language :: English
ISSN :: 01082701 and 16005759
Volume :: 58
Issue :: 5
Database :: Supplemental Index
Journal :: Acta Crystallographica Section C: Crystal Structure Communications
Publication Type :: Periodical
Accession number :: ejs24571249
Full Text :: https://doi.org/10.1107/S0108270102004948

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