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A New Method of Nuclear Methylation of Aromatic Amines and Phenolic Substances

Authors :
BARCLAY, M. G.
BURAWOY, A.
THOMSON, G. H.
Source :
Nature; May 1943, Vol. 151 Issue: 3839 p615-616, 2p
Publication Year :
1943

Abstract

HYDRAZOBENZENE, when heated to high temperatures, decomposes with formation of aniline and azobenzene1, and it is, likely that this reaction starts with the cleavage of an NH–NH linkage forming free radicals, which become stabilized by disproportionation involving undissociated hydrazobenzene:

Details

Language :
English
ISSN :
00280836 and 14764687
Volume :
151
Issue :
3839
Database :
Supplemental Index
Journal :
Nature
Publication Type :
Periodical
Accession number :
ejs23941840
Full Text :
https://doi.org/10.1038/151615a0