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Chiral 1,2‐Bis(phosphetano)benzenes: Preparation and Use in the Ru‐Catalyzed Hydrogenations of Carbonyl Derivatives
- Source :
- Chemistry - A European Journal; April 1999, Vol. 5 Issue: 4 p1160-1165, 6p
- Publication Year :
- 1999
-
Abstract
- Novel,C2‐symmetric 1,2‐bis(phosphetano)benzene ligands(see figure) are readily synthesized from the corresponding diol cyclic sulfates. When complexed to ruthenium, they form powerful catalysts for highly selective hydrogenation of β‐diketones.
Details
- Language :
- English
- ISSN :
- 09476539 and 15213765
- Volume :
- 5
- Issue :
- 4
- Database :
- Supplemental Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Periodical
- Accession number :
- ejs2252679
- Full Text :
- https://doi.org/10.1002/(SICI)1521-3765(19990401)5:4<1160::AID-CHEM1160>3.0.CO;2-3