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Isostructural Single-Chain and Single-Molecule Magnets

Authors :
Feng, Patrick L.
Hendrickson, David N.
Source :
Inorganic Chemistry; 20240101, Issue: Preprints
Publication Year :
2024

Abstract

Isostructural single-chain magnet (SCM) and single-molecule magnets (SMM) with formulas [Mn6X2(salox)6O2(N3)8] (X = MnII(1), CdII(2); H2salox = salicylaldoxime) have been synthesized and magnetically characterized. Complexes 1and 2possess significantly different magnetization reversal barriers of Ueff= 100.3 and 57.0 K, in spite of comparable uniaxial anisotropies (D) and ground state spin values (S). These observations are indicative of the intrinsic spin dynamics in these structurally related yet magnetically distinct SCM/SMM systems.

Details

Language :
English
ISSN :
00201669 and 1520510X
Issue :
Preprints
Database :
Supplemental Index
Journal :
Inorganic Chemistry
Publication Type :
Periodical
Accession number :
ejs21775333
Full Text :
https://doi.org/10.1021/ic101016t