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Experimental and theoretical studies of lifetimes and transition probabilities for Au and relativistic multiconfiguration Dirac-Fock (MCDF) calculations of lifetimes and transitions probabilities in this ion. The work was motivated by significant disagreements between previous experimental 5d<SUP>9</SUP>6p lifetimes, obtained by means of the beam-foil (BF) method and theoretical data based on Hartree-Fock calculations in which relativistic effects were included as perturbations. The new measurements, based on laser-induced fluorescence, support the BF data and are also in excellent agreement with the MCDF results. We confirm that, while computational methods which include perturbative relativistic corrections appear to be adequate for moderately heavy elements such as Ag, fully relativistic calculations are essential for describing systems as heavy as Au.

Authors :
Zhiguo, Zhang
Brage, T
Curtis, L J
Lundberg, H
Martinson, I
Source :
Journal of Physics B: Atomic, Molecular and Optical Physics; February 2002, Vol. 35 Issue: 3 p483-490, 8p
Publication Year :
2002

Details

Language :
English
ISSN :
09534075 and 13616455
Volume :
35
Issue :
3
Database :
Supplemental Index
Journal :
Journal of Physics B: Atomic, Molecular and Optical Physics
Publication Type :
Periodical
Accession number :
ejs1980855