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Experimental and theoretical studies of lifetimes and transition probabilities for Au and relativistic multiconfiguration Dirac-Fock (MCDF) calculations of lifetimes and transitions probabilities in this ion. The work was motivated by significant disagreements between previous experimental 5d<SUP>9</SUP>6p lifetimes, obtained by means of the beam-foil (BF) method and theoretical data based on Hartree-Fock calculations in which relativistic effects were included as perturbations. The new measurements, based on laser-induced fluorescence, support the BF data and are also in excellent agreement with the MCDF results. We confirm that, while computational methods which include perturbative relativistic corrections appear to be adequate for moderately heavy elements such as Ag, fully relativistic calculations are essential for describing systems as heavy as Au.
- Source :
- Journal of Physics B: Atomic, Molecular and Optical Physics; February 2002, Vol. 35 Issue: 3 p483-490, 8p
- Publication Year :
- 2002
Details
- Language :
- English
- ISSN :
- 09534075 and 13616455
- Volume :
- 35
- Issue :
- 3
- Database :
- Supplemental Index
- Journal :
- Journal of Physics B: Atomic, Molecular and Optical Physics
- Publication Type :
- Periodical
- Accession number :
- ejs1980855