Back to Search
Start Over
New approach to the synthesis of optically active trityl systems
- Source :
- Canadian Journal of Chemistry; November 1969, Vol. 47 Issue: 21 p4073-4076, 4p
- Publication Year :
- 1969
-
Abstract
- A new method for the resolution of potentially optically active trityl alcohols is reported. Three trityl alcohols as pilot compounds were converted to hydracrylic acid derivatives. Esterification with diazo-methane was followed by degradation (reverse Michael reaction) to the original alcohols with sodium hydride. The resolution of phenyl-α-naphthyl-p-tolylcarbinol was effected conveniently by this route.
Details
- Language :
- English
- ISSN :
- 00084042 and 14803291
- Volume :
- 47
- Issue :
- 21
- Database :
- Supplemental Index
- Journal :
- Canadian Journal of Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs19726222
- Full Text :
- https://doi.org/10.1139/v69-674