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A mechanistic study of the base-catalyzed methanolysis and hydrolysis of the hydrogen phthalate ester of 4-bromo-4′-nitrobenzhydrol
- Source :
- Canadian Journal of Chemistry; May 1969, Vol. 47 Issue: 9 p1487-1493, 7p
- Publication Year :
- 1969
-
Abstract
- The hydrogen phthalate ester of 4-bromo-4′-nitrobenzhydrol has been subjected to base-catalyzed methanolysis and hydrolysis. In both cases the BAC2 mechanism has been observed. There is no evidence of ortho-carboxylate anion participation (BAC1 mechanism). The results have been substantiated by kinetics, stereochemistry, and 18O isotope studies.
Details
- Language :
- English
- ISSN :
- 00084042 and 14803291
- Volume :
- 47
- Issue :
- 9
- Database :
- Supplemental Index
- Journal :
- Canadian Journal of Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs19725795
- Full Text :
- https://doi.org/10.1139/v69-246