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The Synthesis and Pyrolytic Rearrangement of Phthalate Esters of Some Tertiary Silanols. An Attempt to Prepare a Silicon Carbon Double Bond Species
- Source :
- Canadian Journal of Chemistry; January 1975, Vol. 53 Issue: 1 p67-70, 4p
- Publication Year :
- 1975
-
Abstract
- The synthesis and pyrolysis of the methyl phthalate esters of diphenylmethylsilyl, t-butylsilyl, benzyldiphenylsilyl, and optically active 2-octanol yielded corresponding silyl ethers and phthalic anhydride. In the case of the latter compound, almost complete retention of configuration was observed about the asymmetric carbon atom. A mechanism is proposed for this rearrangement.
Details
- Language :
- English
- ISSN :
- 00084042 and 14803291
- Volume :
- 53
- Issue :
- 1
- Database :
- Supplemental Index
- Journal :
- Canadian Journal of Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs19711115
- Full Text :
- https://doi.org/10.1139/v75-008