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Crystal Structure and Magnetic Properties of LaCo<INF>13—x</INF>Al<INF>x</INF> Compounds

Authors :
Guo, Yongquan
Liang, Jingkui
Liang, Jingkui
Zhang, Xinhui
Zhao, Yanming
Tang, Weihua
Rao, Guanghui
Source :
Physica Status Solidi (A) - Applications and Materials Science; February 1997, Vol. 159 Issue: 2 p297-304, 8p
Publication Year :
1997

Abstract

The crystal structure and magnetic properties of LaCoIii 13—xAl&lt;INF&gt;x&lt;/INF&gt; compounds have been investigated by X-ray powder diffraction and magnetization measurement. X-ray powder diffraction shows that the compounds crystallize in cubic NaZn&lt;INF&gt;13&lt;/INF&gt;-type structure with lattice parameter a = 11.345(2) to 11.473(4) &#197; in the range of x ≤ 2.7, and in the tetragonal Ce&lt;INF&gt;2&lt;/INF&gt;Ni&lt;INF&gt;17&lt;/INF&gt;Si&lt;INF&gt;9&lt;/INF&gt; structure at x = 3. Magnetization measurements reveal that both cubic and tetragonal LaCo&lt;INF&gt;13—x&lt;/INF&gt;Al&lt;INF&gt;x&lt;/INF&gt; are ferromagnetic with Curie temperature higher than 840 K, and the magnetic moment per Co atom in LaCo&lt;INF&gt;13—x&lt;/INF&gt;Al&lt;INF&gt;x&lt;/INF&gt; compounds decreases with Al content.

Details

Language :
English
ISSN :
18626300 and 18626319
Volume :
159
Issue :
2
Database :
Supplemental Index
Journal :
Physica Status Solidi (A) - Applications and Materials Science
Publication Type :
Periodical
Accession number :
ejs1853483
Full Text :
https://doi.org/10.1002/1521-396X(199702)159:2<297::AID-PSSA297>3.0.CO;2-4