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D‐Fructose‐6‐phosphate Aldolase in Organic Synthesis: Cascade Chemical‐Enzymatic Preparation of Sugar‐Related Polyhydroxylated Compounds

Authors :
Concia, Alda Lisa
Lozano, Carles
Castillo, José A.
Parella, Teodor
Joglar, Jesús
Clapés, Pere
Source :
Chemistry - A European Journal; April 2009, Vol. 15 Issue: 15 p3808-3816, 9p
Publication Year :
2009

Abstract

D‐Fructose‐6‐phosphate aldolase (FSA) is a key biocatalystfor the alternative synthetic construction of biologically active products with known therapeutic and research interest or novel structures relevant to drug discovery. Novel aldol addition reactions of dihydroxyacetone and hydroxyacetone to a variety of aldehydes catalyzed by FSA are presented (see scheme).

Details

Language :
English
ISSN :
09476539 and 15213765
Volume :
15
Issue :
15
Database :
Supplemental Index
Journal :
Chemistry - A European Journal
Publication Type :
Periodical
Accession number :
ejs18344359
Full Text :
https://doi.org/10.1002/chem.200802532