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The inductive effect and pπ − dπ conjugation in esters of phosphorus acids
- Source :
- Russian Chemical Bulletin; July 1970, Vol. 19 Issue: 7 p1454-1458, 5p
- Publication Year :
- 1970
-
Abstract
- 1.The kinetics of alkaline and neutral aqueous hydrolysis of ethyl esters of substituted alkylphosphonic acids was studied.2.On the basis of a correlation analysis of data on the hydrolysis of phosphonates and phosphinates the contribution of the inductive effect and p<subscript>p</subscript> - d<subscript>p</subscript> conjugation of the ethoxyl group at phosphorus to the free energy of activation was evaluated.
Details
- Language :
- English
- ISSN :
- 10665285 and 15739171
- Volume :
- 19
- Issue :
- 7
- Database :
- Supplemental Index
- Journal :
- Russian Chemical Bulletin
- Publication Type :
- Periodical
- Accession number :
- ejs16666274
- Full Text :
- https://doi.org/10.1007/BF00853834